Synthesis and Characterization of Some Thallium Cyclopentadienide Fused Ring Pyridazines

Thallium cyclopentadiene (Cp) salts are important precursors for the synthesis of a variety of compounds having materials and commercial applications. The synthesis of 5,6-fused ring thallium Cp pyridazines 2a-d from previously reported 5,6-fused ring pyridazines is described herein. This route was...

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Bibliographic Details
Published in:Synthetic communications 2013-09, Vol.43 (18), p.2441-2451
Main Authors: Young, Jason O. E., Snyder, Chad A., Tice, Nathan C., Sloan, Seth L., Smith, Adam C., Shah, Sana A., Dopierala, Levi A., Crocker, Michael S., Kobayashi, Yuto, Mazzotta, Michael G.
Format: Article
Language:English
Subjects:
1,2-diacylcyclopentadiene
Cyclopentadiene
fulvenes
pyridazines
thallium
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Summary:Thallium cyclopentadiene (Cp) salts are important precursors for the synthesis of a variety of compounds having materials and commercial applications. The synthesis of 5,6-fused ring thallium Cp pyridazines 2a-d from previously reported 5,6-fused ring pyridazines is described herein. This route was quite general, and features an efficient and convenient two-step synthesis of a series of TlCp salts in a THF solution of thallium ethoxide. Full characterization of newly formed TlCp salts 3a-d are reported.
ISSN:0039-7911
1532-2432
DOI:10.1080/00397911.2012.698356