Inside Cover: Chemoselective Oxidative C(CO)C(methyl) Bond Cleavage of Methyl Ketones to Aldehydes Catalyzed by CuI with Molecular Oxygen (Angew. Chem. Int. Ed. 43/2013)

Aldehyde Termination: A novel copper-catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide range of aromatic and aliphatic methyl ketones and chemoselectively produces aldehydes, accompanied by the release of hydrogen (H2 ) and carbon...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2013-10, Vol.52 (43), p.11176-11176
Main Authors: Zhang, Lin, Bi, Xihe, Guan, Xiaoxue, Li, Xingqi, Liu, Qun, Barry, Badru-Deen, Liao, Peiqiu
Format: Article
Language:English
Subjects:
aldehydes
cleavage reactions
copper
ketones
oxygen
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Summary:Aldehyde Termination: A novel copper-catalyzed transformation from methyl ketones into aldehydes has been accomplished. This method is applicable to a wide range of aromatic and aliphatic methyl ketones and chemoselectively produces aldehydes, accompanied by the release of hydrogen (H2 ) and carbon dioxide (CO2 ) as by-products.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201308184