Preparations of Low-Spin Tetra Cyano Iron Complexes of N-Benzyl-1,2-ethanediamine and Its Oxidative Dehydrogenation

The oxidation of tetracyano(N-benzyl-1,2-ethanediamine) with one equivalent oxidant, hydrogen peroxide or peroxodisulfate, under neutral or basic conditions yielded tetracyano(2-benzylimino-ethylamine)ferrate(II), owing to an acceleration of disproportionation by the presence of N-benzyl substituent...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2004-05, Vol.77 (5), p.987
Main Authors: Goto, Masafumi, Ohse, Yasuhiko, Koga, Sayuri, Kudo, Yuka, Kukihara, Rinko, Kurosaki, Hiromasa
Format: Article
Language:English
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Summary:The oxidation of tetracyano(N-benzyl-1,2-ethanediamine) with one equivalent oxidant, hydrogen peroxide or peroxodisulfate, under neutral or basic conditions yielded tetracyano(2-benzylimino-ethylamine)ferrate(II), owing to an acceleration of disproportionation by the presence of N-benzyl substituents. Further oxidation yielded the corresponding conjugated 1,2-diimineferrate(II) complex.
ISSN:0009-2673
1348-0634