Carbocyclization Reaction of Malonate Derivatives with Allylsilane Moiety Mediated by AlCl3-n-Bu3N

Allylsilane bearing malonate moiety underwent intramolecular carbocyclization reaction by means of AlCl3-n-Bu3N to give silyl-substituted cyclopentanes in good yields.

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2007-05, Vol.80 (5), p.972-978
Main Authors: Imazeki, Shigeaki, Kinoshita, Ryohiko, Akiyama, Takahiko
Format: Article
Language:English
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Description
Summary:Allylsilane bearing malonate moiety underwent intramolecular carbocyclization reaction by means of AlCl3-n-Bu3N to give silyl-substituted cyclopentanes in good yields.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.80.972