Novel Photoinduced Reduction of Conjugate Dienes by the Combination of Benzenethiol and Diphenyl Diselenide

By using a binary system that consisted of benzenethiol and diphenyl diselenide under photoirradiation through a Pyrex vessel with a xenon lamp (λ>300 nm), a variety of conjugate dienes could be reduced to the corresponding internal alkenes under mild conditions.

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2007-12, Vol.80 (12), p.2443-2445
Main Authors: Mitamura, Takenori, Imanishi, Yoshiaki, Nomoto, Akihiro, Sonoda, Motohiro, Ogawa, Akiya
Format: Article
Language:English
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Description
Summary:By using a binary system that consisted of benzenethiol and diphenyl diselenide under photoirradiation through a Pyrex vessel with a xenon lamp (λ>300 nm), a variety of conjugate dienes could be reduced to the corresponding internal alkenes under mild conditions.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.80.2443