A Novel Tetranuclear Iron(III) Complex Having L-Alanine Bridges and an Unprecedented (Fe4(O2H) Core

The reacion of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropane-N,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal struct...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters 1996-01, Vol.25 (1), p.61-62
Main Authors: Yano, Shigenobu, Inagaki, Tomoko, Yamada, Yasuko, Kato, Masako, Yamasaki, Mikio, Sakai, Ken, Tsubomura, Taro, Sato, Mitsunobu, Mori, Wasuke, Yamaguchi, Kazuya, Kinoshita, Isamu
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The reacion of L-alanine (L-ala) with Fe(NO3)2·9H2O in the presence of H5dhpta (1,3-diamino-2-hydroxypropane-N,N,N′,N′-tetraacetic acid) and base (NaOH) affords the novel tetranuclear complex Na[Fe4(dhpta)2(O)(OH)(L-ala)2]·6H2O having L-alaninato bridges and an (Fe4(O2H))9+ core whose crystal structure and magnetic properties were determined.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1996.61