Preparation of m-Acylaniline Derivatives by the Reaction of Tricarbonyl(cyclohexadienone O-benzyloxime)iron Complex and Higher Order Cuprates

Reaction of tricarbonyl[(2,3,4,5-η)-2,4-cyclohexadien-1-one O-benzyloxime]iron and organocuprates, followed by the treatment with acetic anhydride and carbon monoxide, affords [(1,2,3,4-η)-1-(N-acetoxy-N-benzyloxyamino)-5-endo-acyl-1,3-cyclohexadiene]tricarbonylirons, which are converted to m-acylan...

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Bibliographic Details
Published in:Chemistry letters 1998-05, Vol.27 (5), p.393-394
Main Authors: Ban, Soo Ho, Hayashi, Yujiro, Narasaka, Koichi
Format: Article
Language:English
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Summary:Reaction of tricarbonyl[(2,3,4,5-η)-2,4-cyclohexadien-1-one O-benzyloxime]iron and organocuprates, followed by the treatment with acetic anhydride and carbon monoxide, affords [(1,2,3,4-η)-1-(N-acetoxy-N-benzyloxyamino)-5-endo-acyl-1,3-cyclohexadiene]tricarbonylirons, which are converted to m-acylaniline derivatives by treating with potassium carbonate.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.1998.393