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Synthesis and Electrochemical Behavior of a New Water Soluble Ca2+-selective Ionophore Based on Calix[4]arene-triacid-monoquinone

A new water-soluble calix[4]arene-triacid-monoquinone 3 has been synthesized and its ion binding properties in aqueous solution were investigated by means of voltammetry and UV-visible spectrophotometry. The electrochemical behavior of 3 is dependent on the concentration of Ca2+ ion rather than that...

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Published in:Chemistry letters 1998-12, Vol.27 (12), p.1225-1226
Main Authors: Chung, Taek Dong, Kang, Sun Kil, Kim, Hasuck, Kim, Joo Ryun, Oh, Weon Seok, Chang, Suk-Kyu
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Language:English
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description A new water-soluble calix[4]arene-triacid-monoquinone 3 has been synthesized and its ion binding properties in aqueous solution were investigated by means of voltammetry and UV-visible spectrophotometry. The electrochemical behavior of 3 is dependent on the concentration of Ca2+ ion rather than that of other alkaline earth metal ions as well as alkali metal cations. The selective response toward Ca2+ was achieved even in the presence of a large excess ( > 1000-fold) of interfering Na+ ion.
doi_str_mv 10.1246/cl.1998.1225
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title Synthesis and Electrochemical Behavior of a New Water Soluble Ca2+-selective Ionophore Based on Calix[4]arene-triacid-monoquinone
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