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Synthesis and Electrochemical Behavior of a New Water Soluble Ca2+-selective Ionophore Based on Calix[4]arene-triacid-monoquinone
A new water-soluble calix[4]arene-triacid-monoquinone 3 has been synthesized and its ion binding properties in aqueous solution were investigated by means of voltammetry and UV-visible spectrophotometry. The electrochemical behavior of 3 is dependent on the concentration of Ca2+ ion rather than that...
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Published in: | Chemistry letters 1998-12, Vol.27 (12), p.1225-1226 |
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container_end_page | 1226 |
container_issue | 12 |
container_start_page | 1225 |
container_title | Chemistry letters |
container_volume | 27 |
creator | Chung, Taek Dong Kang, Sun Kil Kim, Hasuck Kim, Joo Ryun Oh, Weon Seok Chang, Suk-Kyu |
description | A new water-soluble calix[4]arene-triacid-monoquinone 3 has been synthesized and its ion binding properties in aqueous solution were investigated by means of voltammetry and UV-visible spectrophotometry. The electrochemical behavior of 3 is dependent on the concentration of Ca2+ ion rather than that of other alkaline earth metal ions as well as alkali metal cations. The selective response toward Ca2+ was achieved even in the presence of a large excess ( > 1000-fold) of interfering Na+ ion. |
doi_str_mv | 10.1246/cl.1998.1225 |
format | article |
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title | Synthesis and Electrochemical Behavior of a New Water Soluble Ca2+-selective Ionophore Based on Calix[4]arene-triacid-monoquinone |
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