Solid and Solution State Structures of a Reversible Molecular Oxygen-Carrying Molybdenum Porphyrin Dioxygen Complex

The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion...

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Bibliographic Details
Published in:Chemistry letters 2000-02, Vol.29 (2), p.102-103
Main Authors: Fujihara, Tetsuaki, Rees, Nicholas H, Umakoshi, Keisuke, Tachibana, Junichi, Sasaki, Yoichi, McFarlane, William, Imamura, Taira
Format: Article
Language:English
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Summary:The molecular structure of a reversible oxygen carrier, MoVIO(tmp)(O2) has been characterized by X-ray crystallography. Oxo and dioxygen ligands are actually coordinated with cis conformation, which leads to a saddle-like distortion of the porphyrin ring. The result of 2D ROESY shows the distortion of the porphyrin ring is retained in solution.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2000.102