Organogel Formation of Optically Active 1,6-di-O-TIPDS-myo-inositol

Two novel optically active myo-inositol derivatives having a bulky alkyl–silyl group as a hydrophobic part were synthesized. These compounds acted as a gelator toward nonpolar hydrophobic solvents such as n-hexane, cyclohexane, and toluene via the formation of an intermolecular OH···O hydrogen bondi...

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Bibliographic Details
Published in:Chemistry letters 2003-11, Vol.32 (11), p.1042-1043
Main Authors: Hosoda, Asao, Miyake, Yasuhito, Nomura, Eisaku, Taniguchi, Hisaji
Format: Article
Language:English
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Summary:Two novel optically active myo-inositol derivatives having a bulky alkyl–silyl group as a hydrophobic part were synthesized. These compounds acted as a gelator toward nonpolar hydrophobic solvents such as n-hexane, cyclohexane, and toluene via the formation of an intermolecular OH···O hydrogen bonding network.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2003.1042