Organogel Formation of Optically Active 1,6-di-O-TIPDS-myo-inositol

Two novel optically active myo-inositol derivatives having a bulky alkyl–silyl group as a hydrophobic part were synthesized. These compounds acted as a gelator toward nonpolar hydrophobic solvents such as n-hexane, cyclohexane, and toluene via the formation of an intermolecular OH···O hydrogen bondi...

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Published in:Chemistry letters 2003-11, Vol.32 (11), p.1042-1043
Main Authors: Hosoda, Asao, Miyake, Yasuhito, Nomura, Eisaku, Taniguchi, Hisaji
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Language:English
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Nomura, Eisaku
Taniguchi, Hisaji
description Two novel optically active myo-inositol derivatives having a bulky alkyl–silyl group as a hydrophobic part were synthesized. These compounds acted as a gelator toward nonpolar hydrophobic solvents such as n-hexane, cyclohexane, and toluene via the formation of an intermolecular OH···O hydrogen bonding network.
doi_str_mv 10.1246/cl.2003.1042
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title Organogel Formation of Optically Active 1,6-di-O-TIPDS-myo-inositol
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