Cyano-bridged One-dimensional SmIII–FeIII Molecule-based Magnet with an Ordering Temperature of 3.4 K

A new cynao-bridged SmIII–FeIII bimetallic coordination polymer has been prepared by the reaction of (n-Bu4N)3Fe(CN)6 and Sm(NO3)3·6H2O in a DMF–H2O media. The complex consists of alternate Sm(DMF)4(H2O)2 and Fe(CN)6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a mole...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters 2005-09, Vol.34 (9), p.1280-1281
Main Authors: Ge, Chunhua, Kou, Hui-Zhong, Ni, Zhong-Hai, Jiang, Yun-Bo, Zhang, Li-Fang, Cui, Ai-Li, Sato, Osamu
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A new cynao-bridged SmIII–FeIII bimetallic coordination polymer has been prepared by the reaction of (n-Bu4N)3Fe(CN)6 and Sm(NO3)3·6H2O in a DMF–H2O media. The complex consists of alternate Sm(DMF)4(H2O)2 and Fe(CN)6 units bridged by two cis-cyano ligands to form a zigzag chain. It behaves as a molecule-based magnet with Tc = 3.4 K. At 2 K, hysteresis was observed with a coercive field of 200 Oe.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2005.1280