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Preparation of Nanostructured Li1.4Al0.4Ti1.6(PO4)3 Glass-Ceramics by a Citrate Process

A Li1.4Al0.4Ti1.6(PO4)3 gel was successfully prepared by a citrate process and converted into nanostructured and highly Li+-conductive Li1.4Al0.4Ti1.6(PO4)3 glass-ceramics through heat treatment at 700–900 °C. The experimental results indicated that the Li-ion conductivity of the glass-ceramics depe...

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Published in:Chemistry letters 2005-04, Vol.34 (4), p.512-513
Main Authors: Xu, Xiaoxiong, Wen, Zhaoyin, Gu, Zhonghua, Xu, Xiaohe, Lin, Zuxiang
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Language:English
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creator Xu, Xiaoxiong
Wen, Zhaoyin
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description A Li1.4Al0.4Ti1.6(PO4)3 gel was successfully prepared by a citrate process and converted into nanostructured and highly Li+-conductive Li1.4Al0.4Ti1.6(PO4)3 glass-ceramics through heat treatment at 700–900 °C. The experimental results indicated that the Li-ion conductivity of the glass-ceramics depended greatly on the grain size of the conducting phase in the specimens. An excellent room-temperature conductivity as high as 1.36 × 10−3 S cm−1 was obtained, which is one of the highest lithium-ion conductivity for solid electrolytes.
doi_str_mv 10.1246/cl.2005.512
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title Preparation of Nanostructured Li1.4Al0.4Ti1.6(PO4)3 Glass-Ceramics by a Citrate Process
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