Template-assisted Formation of Charge-transfer Complex by a Mixed Supramolecular Ladder Complex

A 2,6-naphthalenediol-modified BisPYBOX (2,6-bis(benzoxazol-2-yl)pyridine (benzoPYBOX)) ligand and a naphthaldiimide-modified BisPYBOX ligand were newly designed and synthesized as a bar for ladder structure formation. The mixing of these two BisPYBOX ligands formed supramolecular ladders along a po...

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Bibliographic Details
Published in:Chemistry letters 2007-02, Vol.36 (2), p.248-249
Main Authors: Sugimoto, Takahiro, Suzuki, Takayuki, Shinkai, Seiji, Sada, Kazuki
Format: Article
Language:English
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Summary:A 2,6-naphthalenediol-modified BisPYBOX (2,6-bis(benzoxazol-2-yl)pyridine (benzoPYBOX)) ligand and a naphthaldiimide-modified BisPYBOX ligand were newly designed and synthesized as a bar for ladder structure formation. The mixing of these two BisPYBOX ligands formed supramolecular ladders along a polymeric secondary dialkylammonium cations as templates to yield charge-transfer (CT) complexes in solution.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2007.248