LIESST Effect and Cooperativity of a 2-D Hofmann-type Compound

2-D Hofmann-type compound [Fe(4-phpy)2Ni(CN)4]·H2O (4-phpy = 4-phenylpyridine) was synthesized and characterized by magnetic susceptibility measurements. The compound exhibited spin-crossover behavior with thermal hysteresis loop and LIESST effect. The activation energy and the tunneling rate consta...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters 2008-03, Vol.37 (3), p.292-293
Main Authors: Nakao, Koji, Hayami, Shinya, Akita, Motoko, Inoue, Katsuya
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:2-D Hofmann-type compound [Fe(4-phpy)2Ni(CN)4]·H2O (4-phpy = 4-phenylpyridine) was synthesized and characterized by magnetic susceptibility measurements. The compound exhibited spin-crossover behavior with thermal hysteresis loop and LIESST effect. The activation energy and the tunneling rate constant were estimated as Ea=773 (cm−1) and kHL(T→0)=4.51×10−6 (s−1) for the compound.
ISSN:0366-7022
1348-0715
DOI:10.1246/cl.2008.292