Seven-coordinate Rhenium(III) Complexes with a Labile Coordination Site Assembled on Indium-doped Tin Oxide (ITO) Electrodes

The complexes containing seven-coordinate bis(terpyridine)rhenium(III)(OH) moiety with phosphonic acid groups on the ligand have been synthesized and attached on indium-doped tin oxide electrodes. The modified electrodes show pH dependent cyclic voltammograms due to proton-coupled electron transfer...

Full description

Saved in:
Bibliographic Details
Published in:Chemistry letters 2010-09, Vol.39 (9), p.986
Main Authors: Sugimoto, Hideki, Tano, Hiroyuki, Miyake, Hiroyuki, Itoh, Shinobu
Format: Article
Language:English
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:The complexes containing seven-coordinate bis(terpyridine)rhenium(III)(OH) moiety with phosphonic acid groups on the ligand have been synthesized and attached on indium-doped tin oxide electrodes. The modified electrodes show pH dependent cyclic voltammograms due to proton-coupled electron transfer and catalyze electrochemical reduction of dioxygen to hydrogen peroxide.
ISSN:0366-7022
1348-0715