Triarylamines on [3]Radialene Scaffold

Hexakis[4-(diarylamino)phenyl][3]radialene derivatives show remarkably low oxidation potentials, suggesting the intramolecular through-space interaction between the facing triarylamine moieties. This through-space interaction is confirmed by the ESR spectrum of the corresponding oxidized species.

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Bibliographic Details
Published in:Chemistry letters 2011-09, Vol.40 (9), p.1033
Main Authors: Matsumoto, Kouzou, Yamada, Nao, Enomoto, Tetsuya, Kurata, Hiroyuki, Kawase, Takeshi, Oda, Masaji
Format: Article
Language:English
Online Access:Get full text
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Summary:Hexakis[4-(diarylamino)phenyl][3]radialene derivatives show remarkably low oxidation potentials, suggesting the intramolecular through-space interaction between the facing triarylamine moieties. This through-space interaction is confirmed by the ESR spectrum of the corresponding oxidized species.
ISSN:0366-7022
1348-0715