Synthesis and Crystal Structure of Zirconium Fluoride, (H2dap)2[Zr2F12]

A new hybrid zirconium fluoride, (H2dap)2[Zr2F12] (dap = C3H10N2), was prepared by a solvothermal method at 190°C under microwave heating. (H2dap)2[Zr2F12] crystallizes in the monoclinic system, P21/n, a = 10.927(3)Å, b = 7.033(3)Å, c = 11.578(5)Å, β = 99.10(3)°. A structure determination, performed...

Full description

Saved in:
Bibliographic Details
Published in:X-ray Structure Analysis Online 2009, Vol.25, pp.37-38
Main Authors: ALI, A. Ben, SMIRI, L. S., LEBLANC, M., MAISONNEUVE, V.
Format: Article
Language:English
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A new hybrid zirconium fluoride, (H2dap)2[Zr2F12] (dap = C3H10N2), was prepared by a solvothermal method at 190°C under microwave heating. (H2dap)2[Zr2F12] crystallizes in the monoclinic system, P21/n, a = 10.927(3)Å, b = 7.033(3)Å, c = 11.578(5)Å, β = 99.10(3)°. A structure determination, performed from single-crystal X-ray diffraction data, led to the reliability factor R/Rw = 0.015/0.042. The structure is built up from ZrF7 polyhedra connected by edges to form Zr2F12 dimers and from diprotonated organic cations.
ISSN:1883-3578
1883-3578
DOI:10.2116/xraystruct.25.37