Palladacycle-Catalyzed Carbonylation of Aryl Iodides or Bromides with Aryl Formates

An efficient palladacycle-catalyzed aromatic carbonylation reaction of aryl formates with aryl iodides or bromides has been developed. Commercially available and easily prepared aryl formates were employed as carbonyl sources without the use of external carbon monoxide. The present catalytic system...

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Bibliographic Details
Published in:Chinese journal of chemistry 2013-12, Vol.31 (12), p.1488-1494
Main Authors: Chen, Guangwei, Leng, Yuting, Yang, Fan, Wang, Shiwei, Wu, Yangjie
Format: Article
Language:English
Subjects:
aryl formates
carbonylation
catalysis
palladacycle
一氧化碳
催化体系
溴化物
甲酸盐
羰基化
芳基碘化物
苯甲酸酯
钯催化
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Summary:An efficient palladacycle-catalyzed aromatic carbonylation reaction of aryl formates with aryl iodides or bromides has been developed. Commercially available and easily prepared aryl formates were employed as carbonyl sources without the use of external carbon monoxide. The present catalytic system shows broad functional group tolerance and affords aryl benzoate derivatives in good to excellent yields.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201300675