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Hydrogen Adsorption Properties of Lantern-Type Dinuclear M(BDC)(DABCO)1⁄2
The hydrogen adsorption properties and uptake capacities of three-dimensional microporous materials of lantern-type dinuclear M(BDC)(DABCO)1⁄2 (M=CoII, CuII, and ZnII; BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane; Co(BDC)(DABCO)1⁄2 (1), Cu(BDC)(DABCO)1⁄2 (2), Zn(BDC)(DABCO)1...
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Published in: | Bulletin of the Chemical Society of Japan 2008-07, Vol.81 (7), p.847-856 |
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container_title | Bulletin of the Chemical Society of Japan |
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creator | Takei, Tohru Kawashima, Jiro Ii, Takato Maeda, Akihiro Hasegawa, Mika Kitagawa, Tamami Ohmura, Tetsushi Ichikawa, Masao Hosoe, Mitsuya Kanoya, Izuru Mori, Wasuke |
description | The hydrogen adsorption properties and uptake capacities of three-dimensional microporous materials of lantern-type dinuclear M(BDC)(DABCO)1⁄2 (M=CoII, CuII, and ZnII; BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane; Co(BDC)(DABCO)1⁄2 (1), Cu(BDC)(DABCO)1⁄2 (2), Zn(BDC)(DABCO)1⁄2 (3)) were investigated at various temperatures of 77–333 K and pressures up to 10 MPa using a PCT automatic measuring system (Sievert-type apparatus). The results indicated that uptake to 4.11, 2.70, and 3.17 wt % of hydrogen can be stored on 1, 2, and 3, respectively, at 77 K. The amounts of hydrogen are adsorbed by all complexes at around room temperature (293 K) and high-pressures are much lower ( |
doi_str_mv | 10.1246/bcsj.81.847 |
format | article |
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The results indicated that uptake to 4.11, 2.70, and 3.17 wt % of hydrogen can be stored on 1, 2, and 3, respectively, at 77 K. The amounts of hydrogen are adsorbed by all complexes at around room temperature (293 K) and high-pressures are much lower (<0.5 wt %). Adsorption isotherms at around room temperature show a linear uptake relationship; all of them follow the Henry’s law. By measuring nitrogen gas adsorption/desorption, all complexes exhibit approximately Type-I isotherms according to the IUPAC classification and possess BET surface areas in the range of 1165 (for 3) to 1595 m2 g−1 (for 1). Further, the thermal stability of all complexes is high, in the range of about 500 K (for 3) to 600 K (for 1). These complexes were synthesized and characterized by X-ray powder diffraction pattern, TG/DTA, FT-IR, surface area analysis, and hydrogen adsorption measurements.</description><identifier>ISSN: 0009-2673</identifier><identifier>EISSN: 1348-0634</identifier><identifier>DOI: 10.1246/bcsj.81.847</identifier><language>eng</language><publisher>Tokyo: The Chemical Society of Japan</publisher><ispartof>Bulletin of the Chemical Society of Japan, 2008-07, Vol.81 (7), p.847-856</ispartof><rights>The Chemical Society of Japan</rights><rights>Copyright Japan Science and Technology Agency 2008</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed><citedby>FETCH-LOGICAL-c2654-b39d093bed3ea8b1dc403afdb13b795a78c47ccb593ecacbf64c899be34931843</citedby><cites>FETCH-LOGICAL-c2654-b39d093bed3ea8b1dc403afdb13b795a78c47ccb593ecacbf64c899be34931843</cites></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Takei, Tohru</creatorcontrib><creatorcontrib>Kawashima, Jiro</creatorcontrib><creatorcontrib>Ii, Takato</creatorcontrib><creatorcontrib>Maeda, Akihiro</creatorcontrib><creatorcontrib>Hasegawa, Mika</creatorcontrib><creatorcontrib>Kitagawa, Tamami</creatorcontrib><creatorcontrib>Ohmura, Tetsushi</creatorcontrib><creatorcontrib>Ichikawa, Masao</creatorcontrib><creatorcontrib>Hosoe, Mitsuya</creatorcontrib><creatorcontrib>Kanoya, Izuru</creatorcontrib><creatorcontrib>Mori, Wasuke</creatorcontrib><title>Hydrogen Adsorption Properties of Lantern-Type Dinuclear M(BDC)(DABCO)1⁄2</title><title>Bulletin of the Chemical Society of Japan</title><addtitle>Bulletin of the Chemical Society of Japan</addtitle><description>The hydrogen adsorption properties and uptake capacities of three-dimensional microporous materials of lantern-type dinuclear M(BDC)(DABCO)1⁄2 (M=CoII, CuII, and ZnII; BDC = 1,4-benzenedicarboxylate, DABCO = 1,4-diazabicyclo[2.2.2]octane; Co(BDC)(DABCO)1⁄2 (1), Cu(BDC)(DABCO)1⁄2 (2), Zn(BDC)(DABCO)1⁄2 (3)) were investigated at various temperatures of 77–333 K and pressures up to 10 MPa using a PCT automatic measuring system (Sievert-type apparatus). The results indicated that uptake to 4.11, 2.70, and 3.17 wt % of hydrogen can be stored on 1, 2, and 3, respectively, at 77 K. The amounts of hydrogen are adsorbed by all complexes at around room temperature (293 K) and high-pressures are much lower (<0.5 wt %). Adsorption isotherms at around room temperature show a linear uptake relationship; all of them follow the Henry’s law. By measuring nitrogen gas adsorption/desorption, all complexes exhibit approximately Type-I isotherms according to the IUPAC classification and possess BET surface areas in the range of 1165 (for 3) to 1595 m2 g−1 (for 1). Further, the thermal stability of all complexes is high, in the range of about 500 K (for 3) to 600 K (for 1). 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The results indicated that uptake to 4.11, 2.70, and 3.17 wt % of hydrogen can be stored on 1, 2, and 3, respectively, at 77 K. The amounts of hydrogen are adsorbed by all complexes at around room temperature (293 K) and high-pressures are much lower (<0.5 wt %). Adsorption isotherms at around room temperature show a linear uptake relationship; all of them follow the Henry’s law. By measuring nitrogen gas adsorption/desorption, all complexes exhibit approximately Type-I isotherms according to the IUPAC classification and possess BET surface areas in the range of 1165 (for 3) to 1595 m2 g−1 (for 1). Further, the thermal stability of all complexes is high, in the range of about 500 K (for 3) to 600 K (for 1). These complexes were synthesized and characterized by X-ray powder diffraction pattern, TG/DTA, FT-IR, surface area analysis, and hydrogen adsorption measurements.</abstract><cop>Tokyo</cop><pub>The Chemical Society of Japan</pub><doi>10.1246/bcsj.81.847</doi><tpages>10</tpages></addata></record> |
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title | Hydrogen Adsorption Properties of Lantern-Type Dinuclear M(BDC)(DABCO)1⁄2 |
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