Kinetic mechanism of combustion of hydrogen–oxygen mixtures

Based on the analysis of the databases published in the scientific literature and concerned with the reaction rate constants in the H 2 /O 2 system, a new kinetic mechanism is suggested for describing the processes of ignition, combustion, and detonation in hydrogen–oxygen gaseous mixtures. Attentio...

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Published in:Journal of engineering physics and thermophysics 2013-09, Vol.86 (5), p.987-995
Main Authors: Gerasimov, G. Ya, Shatalov, O. P.
Format: Article
Language:English
Subjects:
Analysis
Classical Mechanics
Combustion
Complex Systems
Engineering
Engineering Thermodynamics
Heat and Mass Transfer
Heat and Mass Transfer in Combustion Processes
Industrial Chemistry/Chemical Engineering
Peroxides
Thermodynamics
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description Based on the analysis of the databases published in the scientific literature and concerned with the reaction rate constants in the H 2 /O 2 system, a new kinetic mechanism is suggested for describing the processes of ignition, combustion, and detonation in hydrogen–oxygen gaseous mixtures. Attention is mainly focused on consideration of a low-temperature region ( T < 1000 K) where a chain of reactions of the formation and subsequent decomposition of hydrogen peroxide plays the major role in the system ignition. The proposed mechanism has been tested by comparing computational results with available data on measurement of the ignition-delay time in shock tubes.
doi_str_mv 10.1007/s10891-013-0919-7
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subjects Analysis
Classical Mechanics
Combustion
Complex Systems
Engineering
Engineering Thermodynamics
Heat and Mass Transfer
Heat and Mass Transfer in Combustion Processes
Industrial Chemistry/Chemical Engineering
Peroxides
Thermodynamics
title Kinetic mechanism of combustion of hydrogen–oxygen mixtures
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