Synthesis and Properties of the Derivatives of 2,4,6-Tris(Phenoxy)-1,3,5-Triazine

Five derivatives of 2,4,6-tris(phenoxy)-1,3,5-triazine were synthesized and characterized by 1 H NMR, IR and mass spectrometries. The optical and electrochemical properties of the synthesized compounds were studied. Dilute solutions of 1,3,5-triazines compounds in acetonitrile absorb electromagnetic...

Full description

Saved in:
Bibliographic Details
Published in:Molecular Crystals and Liquid Crystals 2014-02, Vol.590 (1), p.73-79
Main Authors: Dainyte, Aiste, Gudeika, Dalius, Buika, Gintaras, Grazulevicius, Juozas Vidas
Format: Article
Language:English
Subjects:
Acetonitrile
band gap
Chemical compounds
Chemical synthesis
Crystals
cyclic voltammetry
Derivatives
Electrons
Energy gaps (solid state)
Infrared radiation
Liquid crystals
Mass spectrometry
Optical properties
Radiation
spectrometry
substituted 1,3,5-triazine
Voltammetry
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Five derivatives of 2,4,6-tris(phenoxy)-1,3,5-triazine were synthesized and characterized by 1 H NMR, IR and mass spectrometries. The optical and electrochemical properties of the synthesized compounds were studied. Dilute solutions of 1,3,5-triazines compounds in acetonitrile absorb electromagnetic radiation in the region of 200-400 nm with the band gaps of 3.96-4.58 eV. Cyclic voltammetry studies revealed that the electron affinities of the synthesized compound range from −3.24 eV to −3.58 eV, and solid state ionization potentials range from 7.20 eV to 8.16 eV.
ISSN:1542-1406
1563-5287
1527-1943
DOI:10.1080/15421406.2013.873850