New silver(I) pyridinecarboxylate complexes: synthesis, characterization, and antimicrobial therapeutic potential

Silver(I) pyridinecarboxylates (AgPIC (1), AgNIC (2), [Ag(HDIPIC)]·0.75H 2 O (3), PIC = picolinate, NIC = nicotinate, HDIPIC = dipicolinate) were prepared by solvothermal syntheses and their characterization were completed by elemental, spectral, and thermal analyses. To assign the pyridinecarboxyla...

Full description

Saved in:
Bibliographic Details
Published in:Journal of coordination chemistry 2014-03, Vol.67 (6), p.1002-1021
Main Authors: Vargova, Z, Almasi, M, Hudecova, D, Titkova, D, Rostasova, I, Zelenak, V, Gyoryova, K
Format: Article
Language:English
Subjects:
Antiinfectives and antibacterials
Antimicrobial activity
Coordination compounds
H NMR spectra
Infrared spectra
Mid-IR spectra
NMR
Nuclear magnetic resonance
Pyridinecarboxylic acids
Silver
Silver(I) complexes
Thermal analysis
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:Silver(I) pyridinecarboxylates (AgPIC (1), AgNIC (2), [Ag(HDIPIC)]·0.75H 2 O (3), PIC = picolinate, NIC = nicotinate, HDIPIC = dipicolinate) were prepared by solvothermal syntheses and their characterization were completed by elemental, spectral, and thermal analyses. To assign the pyridinecarboxylate coordination mode in the complexes, detailed mid-infrared spectral data and Δ(ν as  − ν s ) comparisons were accomplished. In addition, silver(I) pyridinecarboxylate antimicrobial activities and stability by 1 H NMR spectra were determined. Moreover, the spectral, thermal, and antimicrobial properties of silver(I) and previously prepared zinc(II) pyridinecarboxylates were compared and discussed.
ISSN:0095-8972
1029-0389
DOI:10.1080/00958972.2014.906588