Two-step Synthesis of MoS2 Nanotubes using Shock Waves with Lead as Growth Promoter

• Published in: Zeitschrift für anorganische und allgemeine Chemie (1950) 2014-05, Vol.640 (6), p.1152-1158
• Main Authors: Brontvein, Olga, Jayaram, Vishakantaiah, Reddy, K. P. J., Gordon, Jeffrey M., Tenne, Reshef
• Format: Article
• Language: English
• Subjects: Inorganic nanotubes; Lead; MoS2; Shockwave
• ISSN: 0044-2313; 1521-3749
• DOI: 10.1002/zaac.201300329

A new two‐step procedure for the synthesis of MoS2 nanotubes using lead as a growth promoter is reported. In the first step, molybdenum suboxide nanowhiskers containing a small amount of lead atoms were created by exposing a pressed MoS2+Pb mixture to highly compressed shock‐heated argon gas, with estimated temperatures exceeding 9900 K. In the second step, these molybdenum suboxide nanowhiskers served as templates for the sulfidization of the oxide into MoS2 nanotubes (by using H2S gas in a reducing atmosphere at 820 °C). Unlike the case of WS2 nanotubes, the synthesis of a pure phase of MoS2 nanotubes from molybdenum oxide has proven challenging, due mostly to the volatile nature of the latter at the high requisite reaction temperatures (>800 °C). In contrast, the nature and apparent reaction mechanism of the method reported herein are amenable to future scale‐up. The high‐temperature shockwave system should also facilitate the synthesis of new nanostructures from other layered materials.