Method of carbon-based electrode analysis by conductive-atomic force microscopy

• Published in: Micro & nano letters 2014-02, Vol.9 (2), p.69-72
• Main Authors: Majchrzycki, Ł, Nowicki, M, Czajka, R, Lota, K
• Format: Article
• Language: English
• Subjects: Activated carbon; AFM; atomic force microscopy; Carbon; carbon conductive matrix; Carbon nanotubes; carbon‐based electrode analysis method; composite material characterisation method; composite materials; Conducting polymers; conductive‐atomic force microscopy; C−NiO; electrochemical capacitor electrodes; electrochemical electrodes; electrode surface conductivity; Electrodes; less conductive additive distribution; Nanostructure; Nickel; nickel (II) oxide; nickel compounds; nonconductive additive distribution; poly(3,4‐ethylenedioxythiophene); polyaniline; polypyrrole; Polypyrroles; supercapacitors; surface conductivity
• ISSN: 1750-0443; 1750-0443
• DOI: 10.1049/mnl.2013.0683

A novel method of the characterisation of composite materials for electrochemical capacitor electrodes by conductive-atomic force microscopy is reported. The method allowed the analysis of the structure and the distribution of the non-conductive or less conductive additives dispersed in the carbon conductive matrix, which affect the surface conductivity of the electrodes. The composites of activated carbon with nickel (II) oxide, as well as activated carbon or carbon nanotubes with three different conducting polymers – polyaniline, poly(3,4-ethylenedioxythiophene) and polypyrrole – were prepared and tested and analysed by the reported method.