A 2-D Grid Coordination Polymer with an In-plane and Out-of-plane Structure Bridged by Pyrazine Spacers

A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n (2) has been synthesized and structurally characterized. The copper atom in the complex is six‐coordinated in an octahedral geometry. The azide anions coordinated with copper in a 1‐end form, and the perchlorate anions are not coordinated t...

Full description

Saved in:
Bibliographic Details
Published in:Journal of the Chinese Chemical Society (Taipei) 2013-07, Vol.60 (7), p.699-704
Main Authors: Wang, Wen-Zhen, Duan, Yan-Shan, Wang, Jian-Min, Li, Li-Cun, Liao, Dai-Zheng, Ismayilov, Rayyat Huseyn, Wen, Yuh-Sheng, Lee, Gene-Hsiang, Peng, Shie-Ming, Zhu, Yu-Qin
Format: Article
Language:English
Subjects:
2-D grid coordination polymer
Copper(II) complexes
Magnetic interaction
Oligo-a-pyridyl/pyrazylamine ligands
Citations: Items that this one cites
Items that cite this one
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
Description
Summary:A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n (2) has been synthesized and structurally characterized. The copper atom in the complex is six‐coordinated in an octahedral geometry. The azide anions coordinated with copper in a 1‐end form, and the perchlorate anions are not coordinated to copper centers. The structure shows an orthogonal overlap of orbitals through the bridging pyrazine. Extensive hydrogen bonds were observed in 2D networks. Magnetic studies indicate the presence of very weak antiferromagneic coupling between copper(II) ions. A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n has been synthesized and structurally characterized, and magnetic studies indicate the presence of very weak antiferromagneic coupling between copper(II) ions.
ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.201200638