A 2-D Grid Coordination Polymer with an In-plane and Out-of-plane Structure Bridged by Pyrazine Spacers

A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n (2) has been synthesized and structurally characterized. The copper atom in the complex is six‐coordinated in an octahedral geometry. The azide anions coordinated with copper in a 1‐end form, and the perchlorate anions are not coordinated t...

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Published in:Journal of the Chinese Chemical Society (Taipei) 2013-07, Vol.60 (7), p.699-704
Main Authors: Wang, Wen-Zhen, Duan, Yan-Shan, Wang, Jian-Min, Li, Li-Cun, Liao, Dai-Zheng, Ismayilov, Rayyat Huseyn, Wen, Yuh-Sheng, Lee, Gene-Hsiang, Peng, Shie-Ming, Zhu, Yu-Qin
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Language:English
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2-D grid coordination polymer
Copper(II) complexes
Magnetic interaction
Oligo-a-pyridyl/pyrazylamine ligands
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cited_by cdi_FETCH-LOGICAL-c3558-3b184016ab0ce7917c74a85e6742b07005dbcbcd2e32e2ee77a36e8fe53e8293
cites cdi_FETCH-LOGICAL-c3558-3b184016ab0ce7917c74a85e6742b07005dbcbcd2e32e2ee77a36e8fe53e8293
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container_issue 7
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container_title Journal of the Chinese Chemical Society (Taipei)
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creator Wang, Wen-Zhen
Duan, Yan-Shan
Wang, Jian-Min
Li, Li-Cun
Liao, Dai-Zheng
Ismayilov, Rayyat Huseyn
Wen, Yuh-Sheng
Lee, Gene-Hsiang
Peng, Shie-Ming
Zhu, Yu-Qin
description A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n (2) has been synthesized and structurally characterized. The copper atom in the complex is six‐coordinated in an octahedral geometry. The azide anions coordinated with copper in a 1‐end form, and the perchlorate anions are not coordinated to copper centers. The structure shows an orthogonal overlap of orbitals through the bridging pyrazine. Extensive hydrogen bonds were observed in 2D networks. Magnetic studies indicate the presence of very weak antiferromagneic coupling between copper(II) ions. A 2‐D grid copper(II) complex [Cu(μ3‐H2dpzpda)(N3)]n(ClO4)n has been synthesized and structurally characterized, and magnetic studies indicate the presence of very weak antiferromagneic coupling between copper(II) ions.
doi_str_mv 10.1002/jccs.201200638
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subjects 2-D grid coordination polymer
Copper(II) complexes
Magnetic interaction
Oligo-a-pyridyl/pyrazylamine ligands
title A 2-D Grid Coordination Polymer with an In-plane and Out-of-plane Structure Bridged by Pyrazine Spacers
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