Chemoselective Palladium-Catalyzed Oxidation of Vinyl Ether to Acetate Using Hydrogen Peroxide

A practical and environmental‐friendly method was developed to convert vinyl ether into acetate by using a palladium complex with phosphine ligand and hydrogen peroxide. The only by‐product is water. Chemoselective oxidation of vinyl ether and tert‐enamides to form acetate and N‐acetyl amide with hy...

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Bibliographic Details
Published in:Journal of the Chinese Chemical Society (Taipei) 2014-07, Vol.61 (7), p.749-756
Main Authors: Kon, Yoshihiro, Tanaka, Shinji, Nakashima, Takuya, Sato, Kazuhiko, Shimada, Hiromichi
Format: Article
Language:English
Subjects:
Catalysis
Green chemistry
Oxidation
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Summary:A practical and environmental‐friendly method was developed to convert vinyl ether into acetate by using a palladium complex with phosphine ligand and hydrogen peroxide. The only by‐product is water. Chemoselective oxidation of vinyl ether and tert‐enamides to form acetate and N‐acetyl amide with hydrogen peroxide in the presence of palladium complex having phosphine ligand was developed under mild reaction conditions. This process is environmentally friendly because it uses hydrogen peroxide as a clean oxidant, with water being the only byprocuct.
ISSN:0009-4536
2192-6549
DOI:10.1002/jccs.201400058