Syntheses and Solid-State Structures of Et2SbTeEt and Et2BiTeEt

Diethylstibanyl‐ and diethylbismuthanyl telluranes Et2MTeEt (M = Sb 1, Bi 2) as well as tBu3Sb (3) were structurally characterized by single‐crystal X‐ray diffraction. Single crystals of 1–3 were grown by using an IR‐laser‐assisted technique. Compounds 1 and 2 form short intermolecular E···Te intera...

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Bibliographic Details
Published in:European journal of inorganic chemistry 2014-10, Vol.2014 (28), p.4858-4864
Main Authors: Heimann, Stefan, Kuczkowski, Andreas, Bläser, Dieter, Wölper, Christoph, Haack, Rebekka, Jansen, Georg, Schulz, Stephan
Format: Article
Language:English
Subjects:
Antimony
Bismuth
Crystal growth
Structure elucidation
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Summary:Diethylstibanyl‐ and diethylbismuthanyl telluranes Et2MTeEt (M = Sb 1, Bi 2) as well as tBu3Sb (3) were structurally characterized by single‐crystal X‐ray diffraction. Single crystals of 1–3 were grown by using an IR‐laser‐assisted technique. Compounds 1 and 2 form short intermolecular E···Te interactions in the solid state, which were further investigated with dispersion‐corrected density functional theory. Single crystals of Et2M–TeEt (M = Sb 1, Bi 2) as well as tBu3Sb (3) were grown by using an IR‐laser‐assisted technique. Compounds 1 and 2 form short intermolecular E···Te interactions in the solid state, which were further investigated with dispersion‐corrected density functional theory.
ISSN:1434-1948
1099-0682
DOI:10.1002/ejic.201402471