Inside Back Cover: Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System (Angew. Chem. Int. Ed. 46/2014)

We report a highly ordered intercalated hexagonal binary superlattice of hydrophilically functionalized single-walled carbon nanotubes (p-SWNTs) and surfactant (C12 E5 ) cylindrical micelles. When p-SWNTs (with a diameter slightly larger than that of the C12 E5 cylinders) were added to the hexagonal...

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Published in:Angewandte Chemie International Edition 2014-11, Vol.53 (46), p.12643-12643
Main Authors: Lim, Sung-Hwan, Jang, Hyung-Sik, Ha, Jae-Min, Kim, Tae-Hwan, Kwasniewski, Pawel, Narayanan, Theyencheri, Jin, Kyeong Sik, Choi, Sung-Min
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Language:English
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binary superlattices
one-dimensional nanoparticles
self-assembly
shear-induced alignment
single-walled carbon nanotubes
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container_issue 46
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container_title Angewandte Chemie International Edition
container_volume 53
creator Lim, Sung-Hwan
Jang, Hyung-Sik
Ha, Jae-Min
Kim, Tae-Hwan
Kwasniewski, Pawel
Narayanan, Theyencheri
Jin, Kyeong Sik
Choi, Sung-Min
description We report a highly ordered intercalated hexagonal binary superlattice of hydrophilically functionalized single-walled carbon nanotubes (p-SWNTs) and surfactant (C12 E5 ) cylindrical micelles. When p-SWNTs (with a diameter slightly larger than that of the C12 E5 cylinders) were added to the hexagonally packed C12 E5 cylindrical-micellar system, p-SWNTs positioned themselves in such a way that the free-volume entropies for both p-SWNTs and C12 E5 cylinders were maximized, thus resulting in the intercalated hexagonal binary superlattice. In this binary superlattice, a hexagonal array of p-SWNTs is embedded in a honeycomb lattice of C12 E5 cylinders. The intercalated hexagonal binary superlattice can be highly aligned in one direction by an oscillatory shear field and remains aligned after the shear is removed.
doi_str_mv 10.1002/anie.201408889
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subjects binary superlattices
one-dimensional nanoparticles
self-assembly
shear-induced alignment
single-walled carbon nanotubes
title Inside Back Cover: Highly Ordered and Highly Aligned Two-Dimensional Binary Superlattice of a SWNT/Cylindrical-Micellar System (Angew. Chem. Int. Ed. 46/2014)
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