The Electrocatalytic Oxidation of Phenol in Alkaline Electrolyte by Anodes Coated with a Layer of RuO^sub 2 and TiO^sub 2 (DSA) with Participation of Active forms of Oxygen in situ Generated from Hydrogen Peroxide and Molecular Oxygen

Electrocatalytic oxidation of phenol in alkaline electrolyte by by anodes coated with a layer of RuO^sub 2^ and TiO^sub 2^ (DSA) with participation of the active forms of oxygen is investigated. It is established that with AFK addition efficiency of process of oxidation of phenol increases with 87 t...

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Bibliographic Details
Published in:Journal of Siberian Federal University. Chemistry 2014-04, Vol.7 (2), p.200
Main Authors: Kornienko, Galina V, Orlina, Ekaterina A, Chaenko, Natalya V, Kornienko, Vasily L, Maksimov, Nikolay G
Format: Article
Language:Russian
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Summary:Electrocatalytic oxidation of phenol in alkaline electrolyte by by anodes coated with a layer of RuO^sub 2^ and TiO^sub 2^ (DSA) with participation of the active forms of oxygen is investigated. It is established that with AFK addition efficiency of process of oxidation of phenol increases with 87 to 95-96 %. On the basis of given to UF-spectroscopy and voltammetric studies presence of the active forms of oxygen in solution promotes suppression of process of formation of products of a polymeric film that blocks the surface of the electrode and decreases its activity it is established.
ISSN:1998-2836
2313-6049