Microwave-assisted synthesis, structure and properties of a co-crystal compound with 2-ethoxy-6-methyliminomethyl-phenol

A new co-crystal complex [Ni 7 (emmp) 6 (CH 3 O) 2 (OH) 4 ][Ni(emmp) 2 ]·(ClO 4 ) 2 (1, Hemmp is 2-ethoxy-6-methyliminomethyl-phenol) has been synthesised by microwave-assisted method. Complex 1 was characterised by IR spectroscopy, elemental analysis, Raman spectroscopy and X-ray single-crystal dif...

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Bibliographic Details
Published in:Supramolecular chemistry 2015-03, Vol.27 (3), p.161-166
Main Authors: Xiao, Yu, Liu, Yi Qing, Li, Gui, Huang, Pu
Format: Article
Language:English
Subjects:
co-crystal compound
crystal structure
magnetic property
Raman spectra
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Summary:A new co-crystal complex [Ni 7 (emmp) 6 (CH 3 O) 2 (OH) 4 ][Ni(emmp) 2 ]·(ClO 4 ) 2 (1, Hemmp is 2-ethoxy-6-methyliminomethyl-phenol) has been synthesised by microwave-assisted method. Complex 1 was characterised by IR spectroscopy, elemental analysis, Raman spectroscopy and X-ray single-crystal diffraction. The complex consists of a heptanuclear cation cluster [Ni 7 (emmp) 6 (CH 3 O) 2 (OH) 4 ] 2+ , a mononuclear complex [Ni(emmp) 2 ] and two counteranions. Complex 1 displays the contents of antiferromagnetic and ferromagnetic properties.
ISSN:1061-0278
1029-0478
DOI:10.1080/10610278.2014.918268