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Unique mechanical properties of fullerite derivatives synthesized with a catalytic polymerization reaction

Fullerite derivatives synthesized with a catalytic polymerization reaction at a relatively low-pressure range of 0.5–4 GPa show unique mechanical properties: elastic recovery is 98% and hardness possibly approaches 100 GPa. Structure of the samples is also unique: one composes from fragments of C60...

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Bibliographic Details
Published in:MRS communications 2015-03, Vol.5 (1), p.71-75
Main Authors: Popov, M., Blank, V., Perfilov, S., Ovsyannikov, D., Kulnitskiy, B., Tyukalova, E., Prokhorov, V., Maslenikov, I., Perezhogin, I., Skryleva, E., Parkhomenko, Yu
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Language:English
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Summary:Fullerite derivatives synthesized with a catalytic polymerization reaction at a relatively low-pressure range of 0.5–4 GPa show unique mechanical properties: elastic recovery is 98% and hardness possibly approaches 100 GPa. Structure of the samples is also unique: one composes from fragments of C60 molecules linked by the covalent bonds. To obtain the homogeneous crack-free samples, we synthesized B4C–fullerite derivatives composite which show a 550 MPa flexural stress, a 2250 MPa compressive strength, and a 28 GPa hardness and have density of 2.2 g/cm3.
ISSN:2159-6859
2159-6867
DOI:10.1557/mrc.2015.4