Inside Back Cover: Visible-Light-Induced Click Chemistry (Angew. Chem. Int. Ed. 35/2015)

An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Fol...

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2015-08, Vol.54 (35), p.10375-10375
Main Authors: Mueller, Jan O., Schmidt, Friedrich G., Blinco, James P., Barner-Kowollik, Christopher
Format: Article
Language:English
Subjects:
azirine
click chemistry
photochemistry
polymer ligation
visible light
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Summary:An ultrarapid visible-light-driven method for catalyst-free ligation is reported. In their Communication on page10284ff., C. Barner-Kowollik and co-workers describe a highly efficient conjugation between an azirine moiety (white) and diverse dipolarophiles (red) under irradiation from blue LEDs. Following the photogeneration of a nitrile ylide (cyan structure), complete conversion into the cycloadduct takes place through a click-type reaction.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201506194