Studies on anticorrosion properties of polyaniline-TiO 2 blended with acrylic-silicone coating using electrochemical impedance spectroscopy

• Published in: Pigment & resin technology 2016-01, Vol.45 (1), p.18-23
• Main Authors: Mohd Jamari, Siti Khumaira, Kasi, Ramesh, Ismail, Leeana, Mat Nor, Nur Amirah, Subramanian, Ramis Rau, Subramaniam, T. Ramesh, Balakrishnan, Vengadaesvaran, Mohd Arof, Abdul Kariem
• Format: Article
• Language: English
• Subjects: Corrosion potential; Corrosion prevention; Electrodes; Electrolytes; Oxidation; Polymers; Protective coatings; Silicones; Software; Spectrum analysis; Steel; Studies
• ISSN: 0369-9420; 1758-6941
• DOI: 10.1108/PRT-02-2014-0016

Purpose - The purpose of this paper is to study the performance of coatings for corrosion protection. In this research, different compositions of polyaniline (PANI) were added in a pigmented acrylic polyol-silicone coating. The important performance property is corrosion protection. The coatings must be evaluated under corrosive environment. Electrochemical impedance spectroscopy (EIS) is the suitable method to investigate the effect of the addition of PANI in the binder mixture. Design/methodology/approach - The coating resistance, coating capacitance, water uptake and the diffusion coefficient of the coatings were tested for each of the sample. These parameters of the coatings were tested for a period of 60 days of exposure of 3.5 weight per cent solution of sodium chloride salt. EIS results will be further verified by immersion test and salt spray test. Findings - Coating materials developed using 8 and 10 weight per cent of PANI exhibited better coating properties with higher coating resistance for a period 60 days immersion in corrosive environment compared to coatings with lower amount of PANI (2-6 weight per cent). The best coating system obtained the coating resistance value in the range of giga ohms even after the 60th day of exposure. The lowest capacitance value suggested that the coatings have not allowed the electrolyte to permeate to the interface. Water uptake values were found to be in the range of 5 per cent. Salt spray test results showed that the corrosion has initiated at the edges of the scratches only. Practical implications - The study of the effect of conducting polymers in acrylic polyol/silicone resin hybrid binder will be useful for more exploration in coating science. Originality/value - The development of protective hybrid coatings using conducting polymer and TiO 2 particles is new. The results show high coating resistance values.