Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone

Nanoparticles (NPs) derived from earth-abundant metal(0) carbonyls catalyze conversion of bio-derived levulinic acid into [gamma]-valerolactone in up to 93% isolated yield. This sustainable and green route uses non-precious metal catalysts and can be performed in aqueous or ethanol solution without...

Full description

Saved in:
Bibliographic Details
Published in:ChemSusChem 2016-01, Vol.9 (2), p.181
Main Authors: Gowda, Ravikumar R, Chen, Eugene Y-X
Format: Article
Language:English
Subjects:
Earth
Online Access:Get full text
Tags: Add Tag
No Tags, Be the first to tag this record!
cited_by
cites
container_end_page
container_issue 2
container_start_page 181
container_title ChemSusChem
container_volume 9
creator Gowda, Ravikumar R
Chen, Eugene Y-X
description Nanoparticles (NPs) derived from earth-abundant metal(0) carbonyls catalyze conversion of bio-derived levulinic acid into [gamma]-valerolactone in up to 93% isolated yield. This sustainable and green route uses non-precious metal catalysts and can be performed in aqueous or ethanol solution without using hydrogen gas as the hydrogen source. Generation of metal NPs using microwave irradiation greatly enhances the rate of the conversion, enables the use of ethanol as both solvent and hydrogen source without forming the undesired ethyl levulinate, and affords recyclable polymer-stabilized NPs.
doi_str_mv 10.1002/cssc.201501402
format article
fullrecord <record><control><sourceid>proquest</sourceid><recordid>TN_cdi_proquest_journals_1758611642</recordid><sourceformat>XML</sourceformat><sourcesystem>PC</sourcesystem><sourcerecordid>3928097161</sourcerecordid><originalsourceid>FETCH-LOGICAL-g150t-a73a0a3608127067be58f33397641d07ba77036c4d2d8b6dc276c2f33da241f13</originalsourceid><addsrcrecordid>eNo9T0tLAzEYDKJgrV49Bzyv5rXJ9lhKtUJ9oFUEkfJtkq1b0qQm2UL_hL_ZBcXTDDPDDIPQOSWXlBB2pVPSl4zQklBB2AEa0EqKopTi7fCfc3qMTlJaEyLJSMoB-n6yeq8d1M7iKcT8WYzrzhvwGd_ZDA7fgw_b3mh1n5hAL-1TTrgJET9bZ3VudxYvIvjU2IhnexPDynrIbfA4NHhud51rfavxWLcG54AfYzCdtvh9BZsNfBSv4GwMDnQO3p6iowZcsmd_OEQv19PFZFbMH25uJ-N5serv5QIUBwJckooyRaSqbVk1nPORkoIaompQinCphWGmqqXRTEnN-oQBJmhD-RBd_PZuY_jqbMrLdeii7yeXVJWVpFQKxn8A0pVn9g</addsrcrecordid><sourcetype>Aggregation Database</sourcetype><iscdi>true</iscdi><recordtype>article</recordtype><pqid>1758611642</pqid></control><display><type>article</type><title>Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone</title><source>Wiley</source><creator>Gowda, Ravikumar R ; Chen, Eugene Y-X</creator><creatorcontrib>Gowda, Ravikumar R ; Chen, Eugene Y-X</creatorcontrib><description>Nanoparticles (NPs) derived from earth-abundant metal(0) carbonyls catalyze conversion of bio-derived levulinic acid into [gamma]-valerolactone in up to 93% isolated yield. This sustainable and green route uses non-precious metal catalysts and can be performed in aqueous or ethanol solution without using hydrogen gas as the hydrogen source. Generation of metal NPs using microwave irradiation greatly enhances the rate of the conversion, enables the use of ethanol as both solvent and hydrogen source without forming the undesired ethyl levulinate, and affords recyclable polymer-stabilized NPs.</description><identifier>ISSN: 1864-5631</identifier><identifier>EISSN: 1864-564X</identifier><identifier>DOI: 10.1002/cssc.201501402</identifier><language>eng</language><publisher>Weinheim: Wiley Subscription Services, Inc</publisher><subject>Earth</subject><ispartof>ChemSusChem, 2016-01, Vol.9 (2), p.181</ispartof><rights>2016 WILEY-VCH Verlag GmbH &amp; Co. KGaA, Weinheim</rights><lds50>peer_reviewed</lds50><woscitedreferencessubscribed>false</woscitedreferencessubscribed></display><links><openurl>$$Topenurl_article</openurl><openurlfulltext>$$Topenurlfull_article</openurlfulltext><thumbnail>$$Tsyndetics_thumb_exl</thumbnail><link.rule.ids>314,780,784,27924,27925</link.rule.ids></links><search><creatorcontrib>Gowda, Ravikumar R</creatorcontrib><creatorcontrib>Chen, Eugene Y-X</creatorcontrib><title>Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone</title><title>ChemSusChem</title><description>Nanoparticles (NPs) derived from earth-abundant metal(0) carbonyls catalyze conversion of bio-derived levulinic acid into [gamma]-valerolactone in up to 93% isolated yield. This sustainable and green route uses non-precious metal catalysts and can be performed in aqueous or ethanol solution without using hydrogen gas as the hydrogen source. Generation of metal NPs using microwave irradiation greatly enhances the rate of the conversion, enables the use of ethanol as both solvent and hydrogen source without forming the undesired ethyl levulinate, and affords recyclable polymer-stabilized NPs.</description><subject>Earth</subject><issn>1864-5631</issn><issn>1864-564X</issn><fulltext>true</fulltext><rsrctype>article</rsrctype><creationdate>2016</creationdate><recordtype>article</recordtype><recordid>eNo9T0tLAzEYDKJgrV49Bzyv5rXJ9lhKtUJ9oFUEkfJtkq1b0qQm2UL_hL_ZBcXTDDPDDIPQOSWXlBB2pVPSl4zQklBB2AEa0EqKopTi7fCfc3qMTlJaEyLJSMoB-n6yeq8d1M7iKcT8WYzrzhvwGd_ZDA7fgw_b3mh1n5hAL-1TTrgJET9bZ3VudxYvIvjU2IhnexPDynrIbfA4NHhud51rfavxWLcG54AfYzCdtvh9BZsNfBSv4GwMDnQO3p6iowZcsmd_OEQv19PFZFbMH25uJ-N5serv5QIUBwJckooyRaSqbVk1nPORkoIaompQinCphWGmqqXRTEnN-oQBJmhD-RBd_PZuY_jqbMrLdeii7yeXVJWVpFQKxn8A0pVn9g</recordid><startdate>20160101</startdate><enddate>20160101</enddate><creator>Gowda, Ravikumar R</creator><creator>Chen, Eugene Y-X</creator><general>Wiley Subscription Services, Inc</general><scope>7SR</scope><scope>8BQ</scope><scope>8FD</scope><scope>JG9</scope><scope>K9.</scope></search><sort><creationdate>20160101</creationdate><title>Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone</title><author>Gowda, Ravikumar R ; Chen, Eugene Y-X</author></sort><facets><frbrtype>5</frbrtype><frbrgroupid>cdi_FETCH-LOGICAL-g150t-a73a0a3608127067be58f33397641d07ba77036c4d2d8b6dc276c2f33da241f13</frbrgroupid><rsrctype>articles</rsrctype><prefilter>articles</prefilter><language>eng</language><creationdate>2016</creationdate><topic>Earth</topic><toplevel>peer_reviewed</toplevel><toplevel>online_resources</toplevel><creatorcontrib>Gowda, Ravikumar R</creatorcontrib><creatorcontrib>Chen, Eugene Y-X</creatorcontrib><collection>Engineered Materials Abstracts</collection><collection>METADEX</collection><collection>Technology Research Database</collection><collection>Materials Research Database</collection><collection>ProQuest Health &amp; Medical Complete (Alumni)</collection><jtitle>ChemSusChem</jtitle></facets><delivery><delcategory>Remote Search Resource</delcategory><fulltext>fulltext</fulltext></delivery><addata><au>Gowda, Ravikumar R</au><au>Chen, Eugene Y-X</au><format>journal</format><genre>article</genre><ristype>JOUR</ristype><atitle>Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone</atitle><jtitle>ChemSusChem</jtitle><date>2016-01-01</date><risdate>2016</risdate><volume>9</volume><issue>2</issue><spage>181</spage><pages>181-</pages><issn>1864-5631</issn><eissn>1864-564X</eissn><abstract>Nanoparticles (NPs) derived from earth-abundant metal(0) carbonyls catalyze conversion of bio-derived levulinic acid into [gamma]-valerolactone in up to 93% isolated yield. This sustainable and green route uses non-precious metal catalysts and can be performed in aqueous or ethanol solution without using hydrogen gas as the hydrogen source. Generation of metal NPs using microwave irradiation greatly enhances the rate of the conversion, enables the use of ethanol as both solvent and hydrogen source without forming the undesired ethyl levulinate, and affords recyclable polymer-stabilized NPs.</abstract><cop>Weinheim</cop><pub>Wiley Subscription Services, Inc</pub><doi>10.1002/cssc.201501402</doi></addata></record>
fulltext fulltext
identifier ISSN: 1864-5631
ispartof ChemSusChem, 2016-01, Vol.9 (2), p.181
issn 1864-5631
1864-564X
language eng
recordid cdi_proquest_journals_1758611642
source Wiley
subjects Earth
title Recyclable Earth-Abundant Metal Nanoparticle Catalysts for Selective Transfer Hydrogenation of Levulinic Acid to Produce [gamma]-Valerolactone
url http://sfxeu10.hosted.exlibrisgroup.com/loughborough?ctx_ver=Z39.88-2004&ctx_enc=info:ofi/enc:UTF-8&ctx_tim=2025-01-07T15%3A44%3A02IST&url_ver=Z39.88-2004&url_ctx_fmt=infofi/fmt:kev:mtx:ctx&rfr_id=info:sid/primo.exlibrisgroup.com:primo3-Article-proquest&rft_val_fmt=info:ofi/fmt:kev:mtx:journal&rft.genre=article&rft.atitle=Recyclable%20Earth-Abundant%20Metal%20Nanoparticle%20Catalysts%20for%20Selective%20Transfer%20Hydrogenation%20of%20Levulinic%20Acid%20to%20Produce%20%5Bgamma%5D-Valerolactone&rft.jtitle=ChemSusChem&rft.au=Gowda,%20Ravikumar%20R&rft.date=2016-01-01&rft.volume=9&rft.issue=2&rft.spage=181&rft.pages=181-&rft.issn=1864-5631&rft.eissn=1864-564X&rft_id=info:doi/10.1002/cssc.201501402&rft_dat=%3Cproquest%3E3928097161%3C/proquest%3E%3Cgrp_id%3Ecdi_FETCH-LOGICAL-g150t-a73a0a3608127067be58f33397641d07ba77036c4d2d8b6dc276c2f33da241f13%3C/grp_id%3E%3Coa%3E%3C/oa%3E%3Curl%3E%3C/url%3E&rft_id=info:oai/&rft_pqid=1758611642&rft_id=info:pmid/&rfr_iscdi=true