Biomolecule-Assisted Route to Prepare Titania Mesoporous Hollow Structures

• Published in: Chemistry : a European journal 2011-10, Vol.17 (41), p.11535-11541
• Main Authors: Ding, Shangjun, Wang, Yaoming, Hong, Zhanglian, Lü, Xujie, Wan, Dongyun, Huang, Fuqiang
• Format: Article
• Language: English
• Subjects: Amino acids; Amino Acids - chemistry; Arginine - chemistry; Catalysis; Chemistry; Coloring Agents - chemistry; isoelectric points; Lysine - chemistry; mesoporous materials; Models, Molecular; Molecular Structure; nanostructures; Nanostructures - chemistry; Photochemistry; Porosity; Solar Energy; Temperature; titanium; Titanium - chemistry
• ISSN: 0947-6539; 1521-3765
• DOI: 10.1002/chem.201101314

Amino acids, as a particularly important type of biomolecules, have been used as multifunctional templates to intelligently construct mesoporous TiO2 hollow structures through a simple solvothermal reaction. The structure‐directing behaviors of various amino acids were systematically investigated, and it was found that these biomolecules possess the general capability to assist mesoporous TiO2 hollow‐sphere formation. At the same time, the nanostructures of the obtained TiO2 are highly dependent on the isoelectric points (pI) of amino acids. Their molecular‐structure variations can lead to pI differences and significantly influence the final TiO2 morphologies. Higher‐pI amino acids (e.g., L‐lysine and L‐arginine) have better structure‐directing abilities to generate nanosheet‐assembled hollow spheres and yolk/shell structures. The specific morphologies and mesopore size of these novel hollow structures can also be tuned by adjusting the titanium precursor concentration. Heat treatment in air and vacuum was further conducted to transform the as‐prepared structures to porous nanoparticle‐assembled hollow TiO2 and TiO2/carbon nanocomposites, which may be potentially applied in the fields of photocatalysts, dye‐sensitized solar cells, and Li batteries. This study provides some enlightenment on the design of novel templates by taking advantage of biomolecules. Magnum pI: Amino acids exhibit multifunctional template effects and possess the general capability to construct mesoporous TiO2 hollow spheres through solvothermal reactions. The obtained nanostructures of TiO2 are highly dependent on the isoelectric points (pI) of amino acids. Molecular‐structure variations lead to pI differences and significantly influence the final TiO2 morphologies (see figure).