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Wormlike Micelle Formation and Rheological Behavior in the Aqueous Solutions of Mixed Sulfate Gemini Surfactant without Spacer Group and Dodecyltrimethylammonium Bromide

The rheological behavior of the aqueous solutions of mixed sulfate gemini surfactant with no spacer group, referred to as d-C12S, and dodecyltrimethylammonium bromide (C12TABr) at a total concentration of 100 mmol,L-1 but different molar ratios of ClzTABr to d-C12S (a1) was investigated using steady...

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Published in:Chinese journal of chemistry 2011-10, Vol.29 (10), p.2003-2006
Main Author: 裴晓梅 赵剑曦 游毅 刘玉芳 魏西莲
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cited_by cdi_FETCH-LOGICAL-c4478-592d07f7ddca6fc88ebe1a5d6851f1265949054c05077fa1705a848369a185c83
cites cdi_FETCH-LOGICAL-c4478-592d07f7ddca6fc88ebe1a5d6851f1265949054c05077fa1705a848369a185c83
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creator 裴晓梅 赵剑曦 游毅 刘玉芳 魏西莲
description The rheological behavior of the aqueous solutions of mixed sulfate gemini surfactant with no spacer group, referred to as d-C12S, and dodecyltrimethylammonium bromide (C12TABr) at a total concentration of 100 mmol,L-1 but different molar ratios of ClzTABr to d-C12S (a1) was investigated using steady rate and frequency sweep measurements. The wormlike micelles were formed over a narrow a1 range of 0.20-0.27. The viscoelastic solutions exhibited Maxwell fluid behavior. At the optimum molar ratio of 0.25, the zero-shear viscosity was as high as 600 paos and the length of the mixed wormlike micelle was about 0.45-0.85 pm. The present result provides an exam- ple to construct long wormlike micelles by anionic gemini surfactant.
doi_str_mv 10.1002/cjoc.201180348
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subjects aggregation
gemini surfactant with no spacer group
Gemini表面活性剂
Maxwell流体
mixed wormlike micelles
viscoelastic properties
十二烷基三甲基溴化铵
水溶液
流变行为
混合
硫酸
蠕虫状胶束
title Wormlike Micelle Formation and Rheological Behavior in the Aqueous Solutions of Mixed Sulfate Gemini Surfactant without Spacer Group and Dodecyltrimethylammonium Bromide
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