Electrosynthesis of Chirality Conducting Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] with Good Blue Light-Emitting Properties

Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] （PN9FPA） films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycarbonyl）- L-phenylalanine （N9FPA） in boron trifluoride diethyletherate （BFEE）. Fourier transform inf...

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Bibliographic Details
Published in:Chinese journal of chemistry 2012-03, Vol.30 (3), p.507-511
Main Author: 来存远 郭文娟 唐新德 裴梅山
Format: Article
Language:English
Subjects:
blue-light emitter
chirality
Fluorescence
Fourier transforms
good solubility
L-苯丙氨酸
poly[N-(9-fluorenylmethoxycarbonyl)-L-phenylalanine]
Spectrum analysis
傅里叶变换红外光谱
发光性质
导电
手性
芴
荧光性能
蓝色
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Summary:Poly[N-（9-fluorenylmethoxycarbonyl）-L-phenylalanine] （PN9FPA） films with good fluorescence properties and chirality were prepared electrochemically by direct anodic oxidation of N-（9-fluorenylmethoxycarbonyl）- L-phenylalanine （N9FPA） in boron trifluoride diethyletherate （BFEE）. Fourier transform infrared spectroscopy measurement showed that the polymerization of N9FPA occurred mainly at the C（2） and C（7） positions. The fluo- rescence spectra indicated that PN9FPA films were blue-light emitters. In addition, the structures and properties of the monomer and the polymers were characterized and evaluated with CV, UV, TGA and SEM.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201100087