Iron-Mediated Chlorotrifluoromethylation of Alkenes with Sodium Trifluoromethanesulfinate

An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride （FeC13） as the CI source and the Langlois reagent （CF3SO2Na） as the CF3 source. It provides a convenient pathway towards a wide range of c...

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Bibliographic Details
Published in:Chinese journal of chemistry 2016-05, Vol.34 (5), p.465-468
Main Authors: Yang, Bin, Xu, Xiu-Hua, Qing, Feng-Ling
Format: Article
Language:English
Subjects:
alkene
chlorotrifluoromethylation
FeCl3
Langlois reagent
radical
三分量
三氟甲基
三氯化铁
介导
烯烃
磺酸钠
脂肪族
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Summary:An iron-mediated three-component chlorotrifluoromethylation of both styrenes and aliphatic alkenes has been presented here. This reaction employs ferric chloride （FeC13） as the CI source and the Langlois reagent （CF3SO2Na） as the CF3 source. It provides a convenient pathway towards a wide range of chlorotrifluoromethylated compounds.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201500641