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Magnetoresistive properties of Ni-doped La^sub 0.7^Sr^sub 0.3^MnO3 manganites
La0.7Sr0.3Mn1-xNixO3 (x = 0, 0.025, 0.050 and 0.075) ceramics were prepared by the conventional solid-state reaction method. The partial substitution of Mn by Ni2+ leads to a decrease in cell volume as well as a structural transition from the rhombohedral to the orthorhombic structure. Ni2+ doping i...
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Published in: | Rare metals 2016-07, Vol.35 (7), p.551 |
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Main Authors: | , , , , |
Format: | Article |
Language: | English |
Online Access: | Get full text |
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Summary: | La0.7Sr0.3Mn1-xNixO3 (x = 0, 0.025, 0.050 and 0.075) ceramics were prepared by the conventional solid-state reaction method. The partial substitution of Mn by Ni2+ leads to a decrease in cell volume as well as a structural transition from the rhombohedral to the orthorhombic structure. Ni2+ doping increases the electrical resistivity, decreases the semiconductor-metal transition temperature (T ms) and relatively enhances the room temperature magnetoresistance (MR), especially in x = 0.025 and around T ms. With respect to conduction mechanism, the small polaron hopping (SPH) and the variable range hopping (VRH) models were used to examine conduction in the semiconducting region. |
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ISSN: | 1001-0521 1867-7185 |
DOI: | 10.1007/s12598-015-0465-x |