Frontispiece: The 2-Arsaethynolate Anion: Synthesis and Reactivity Towards Heteroallenes

Anions. The synthesis of the 2‐arsaethynolate anion AsCO− through carbonylation of NaAsH2 is described in the Communication by J. M. Goicoechea and A. Hinz on page 8536 ff. AsCO− can undergo cyclization with unsaturated substrates to yield novel heterocyclic species.

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Bibliographic Details
Published in:Angewandte Chemie International Edition 2016-07, Vol.55 (30), p.n/a
Main Authors: Hinz, Alexander, Goicoechea, Jose M.
Format: Article
Language:English
Subjects:
arsenic
cluster compounds
cycloadditions
reaction mechanisms
structure elucidation
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Description
Summary:Anions. The synthesis of the 2‐arsaethynolate anion AsCO− through carbonylation of NaAsH2 is described in the Communication by J. M. Goicoechea and A. Hinz on page 8536 ff. AsCO− can undergo cyclization with unsaturated substrates to yield novel heterocyclic species.
ISSN:1433-7851
1521-3773
DOI:10.1002/anie.201683061