Gyroscopic behavior exhibited by the optical Kerr effect in bimetallic Au–Pt nanoparticles suspended in ethanol

The modification in the third-order nonlinear optical response exhibited by rotating bimetallic Au–Pt nanoparticles in an ethanol solution was analyzed. The samples were prepared by a sol–gel processing route. The anisotropy associated to the elemental composition of the nanoparticles was confirmed...

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Published in:Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology 2016-07, Vol.18 (7), p.1, Article 204
Main Authors: Fernández-Valdés, D., Torres-Torres, C., Martínez-González, C. L., Trejo-Valdez, M., Hernández-Gómez, L. H., Torres-Martínez, R.
Format: Article
Language:English
Subjects:
Anisotropy
Characterization and Evaluation of Materials
Chemical composition
Chemistry and Materials Science
Ethanol
Inorganic Chemistry
Lasers
Materials Science
Nanoparticles
Nanotechnology
Optical Devices
Optics
Photonics
Physical Chemistry
Research Paper
Ultraviolet spectroscopy
X-ray spectroscopy
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container_title Journal of nanoparticle research : an interdisciplinary forum for nanoscale science and technology
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creator Fernández-Valdés, D.
Torres-Torres, C.
Martínez-González, C. L.
Trejo-Valdez, M.
Hernández-Gómez, L. H.
Torres-Martínez, R.
description The modification in the third-order nonlinear optical response exhibited by rotating bimetallic Au–Pt nanoparticles in an ethanol solution was analyzed. The samples were prepared by a sol–gel processing route. The anisotropy associated to the elemental composition of the nanoparticles was confirmed by high-resolution transmission electron microscopy and energy-dispersive X-ray spectroscopy measurements. The size of the nanoparticles varies in the range from 9 to 13 nm, with an average size of 11 nm. Changes in the spatial orientation of the nanomaterials automatically generated a variation in their plasmonic response evaluated by UV–Vis spectroscopy. A two-wave mixing experiment was conducted to explore an induced birefringence at 532 nm wavelength with nanosecond pulses interacting with the samples. A strong optical Kerr effect was identified to be the main responsible effect for the third-order nonlinear optical phenomenon exhibited by the nanoparticles. It was estimated that the rotation of inhomogeneous nanostructures can provide a remarkable change in the participation of different surface plasmon resonances, if they correspond to multimetallic nanoparticles. Potential applications for developing low-dimensional gyroscopic systems can be contemplated.
doi_str_mv 10.1007/s11051-016-3510-2
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source Springer Nature
subjects Anisotropy
Characterization and Evaluation of Materials
Chemical composition
Chemistry and Materials Science
Ethanol
Inorganic Chemistry
Lasers
Materials Science
Nanoparticles
Nanotechnology
Optical Devices
Optics
Photonics
Physical Chemistry
Research Paper
Ultraviolet spectroscopy
X-ray spectroscopy
title Gyroscopic behavior exhibited by the optical Kerr effect in bimetallic Au–Pt nanoparticles suspended in ethanol
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