Nitration-Oximization of Styrene Derivatives with tert-Butyl Nitrite＂ Synthesis of a-Nitrooximes

A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite（t-BuONO） in DMSO was developed. The present method offers a convenient and practical approach for the syn-thesis of a-nitrooximes in moderate to high yields. The salient features entail mild re...

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Bibliographic Details
Published in:Chinese journal of chemistry 2016-08, Vol.34 (8), p.830-838
Main Authors: Chumnanvej, Napasawan, Katrun, Praewpan, Pohmakotr, Manat, Reutrakul, Vichai, Soorukram, Darunee, Kuhakarn, Chutima
Format: Article
Language:English
Subjects:
Chemical industry
nitration-oximization
nitrite
Styrene
styrenes
tert-butyl
α-nitrooximes
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Summary:A highly efficient method for direct nitration-oximization of styrene derivatives using tert-butyl nitrite（t-BuONO） in DMSO was developed. The present method offers a convenient and practical approach for the syn-thesis of a-nitrooximes in moderate to high yields. The salient features entail mild reaction conditions, metal-freereagent, environmentally benign solvent and simple experimental procedure.
ISSN:1001-604X
1614-7065
DOI:10.1002/cjoc.201600167