Numerical Simulation of Copper Migration in Single Crystal CdTe

Absorber material with high and stable p-type doping that does not impede free carrier lifetime is the key component enabling efficiency and stability improvements in thin-film CdTe technology. To better understand the compensation mechanism and the metastable effects related to Cu acceptors, the mo...

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Bibliographic Details
Published in:IEEE journal of photovoltaics 2016-09, Vol.6 (5), p.1286-1291
Main Authors: Da Guo, Tian Fang, Moore, Andrew, Brinkman, Daniel, Akis, Richard, Krasikov, Dmitry, Sankin, Igor, Ringhofer, Christian, Vasileska, Dragica
Format: Article
Language:English
Subjects:
Annealing
ANNEALING PROCESSES
Cadmium compounds
Cadmium telluride
Carrier transport
Compensation
COMPUTER SIMULATION
Cooling
Copper
II-VI semiconductor materials
MATHEMATICAL ANALYSIS
Mathematical model
Mathematical models
Migration
numerical simulation
photovoltaic (PV) device
Photovoltaic systems
Point defects
Semiconductor process modeling
Single crystals
THIN FILMS
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Summary:Absorber material with high and stable p-type doping that does not impede free carrier lifetime is the key component enabling efficiency and stability improvements in thin-film CdTe technology. To better understand the compensation mechanism and the metastable effects related to Cu acceptors, the most common p-type dopant in CdTe, i.e., a detailed kinetic model describing the behavior of intrinsic and Cu-related defects in this material, has been developed and applied for the first time. Migration and reactions of these point defects in single crystal CdTe have been investigated by solving diffusion-reaction equations in the time-space domain self-consistently with free carrier transport. The simulation results supported by reasonable match to experimental data have shed light on the nature of limited Cu incorporation (also known as the Cu solubility limits) and Cu self-compensation during the annealing and cooling processes.
ISSN:2156-3381
2156-3403
DOI:10.1109/JPHOTOV.2016.2571626