Inside Cover: Comparative Study of Bifunctional Mononuclear and Dinuclear Amidoiridium Complexes with Chiral C−N Chelating Ligands for the Asymmetric Transfer Hydrogenation of Ketones (Chem. Asian J. 20/2016)

Azairidacycles derived from protic benzylamines have been utilized as powerful hydrogen‐transfer catalysts for ketones and alcohols. The chiral amidoiridium complexes are accessible from (R)‐5‐amino‐6,7,8,9‐tetrahydro‐5H‐benzocycloheptene and (R)‐1‐phenyl‐2,2‐dimethylpropylamine, whereas O‐silylated...

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Published in:Chemistry, an Asian journal an Asian journal, 2016-10, Vol.11 (20), p.2809-2809
Main Authors: Sato, Yasuhiro, Kayaki, Yoshihito, Ikariya, Takao
Format: Article
Language:English
Subjects:
asymmetric catalysis
Chemistry
cooperative effects
hydrogen transfer
iridium
ketones
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Kayaki, Yoshihito
Ikariya, Takao
description Azairidacycles derived from protic benzylamines have been utilized as powerful hydrogen‐transfer catalysts for ketones and alcohols. The chiral amidoiridium complexes are accessible from (R)‐5‐amino‐6,7,8,9‐tetrahydro‐5H‐benzocycloheptene and (R)‐1‐phenyl‐2,2‐dimethylpropylamine, whereas O‐silylated (S)‐2‐amino‐2‐phenylethanols afford amido‐bridged dimers. The preferable catalytic performance of the mononuclear complexes corroborates that the 16‐electron structure is vital for the smooth H+/H– transfer based on the metal/NH cooperative effect. More information can be found in the Full Paper by Yoshihito Kayaki, Takao Ikariya et al. on page 2924 in Issue 20, 2016 (DOI: 10.1002/asia.201600955).
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subjects asymmetric catalysis
Chemistry
cooperative effects
hydrogen transfer
iridium
ketones
title Inside Cover: Comparative Study of Bifunctional Mononuclear and Dinuclear Amidoiridium Complexes with Chiral C−N Chelating Ligands for the Asymmetric Transfer Hydrogenation of Ketones (Chem. Asian J. 20/2016)
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