Novel phosphonium salt for paste electrode to study the redox properties of insoluble compounds

A new carbon paste electrode is described, which contains the room temperature ionic liquid tri(tert-butyl)(decyl)phosphonium tetrafluoroborate as a binder. The advantages of this electrode are a high conductivity, very wide electrochemical window (5.4 V from 2.7 V to −2.7 V, one of the widest ever...

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Bibliographic Details
Published in:Phosphorus, sulfur, and silicon and the related elements sulfur, and silicon and the related elements, 2016-12, Vol.191 (11-12), p.1611-1612
Main Authors: Khrizanforov, M. N., Shekurov, R. P., Ermolaev, V.V., Arkhipova, D. M., Miluykov, V. A., Kataeva, O. N., Khrizanforova, V. V., Budnikova, Y. H.
Format: Article
Language:English
Subjects:
Cyclic voltammetry
electrochemical properties
ferrocene derivative
paste electrode
phosphonium salt
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Summary:A new carbon paste electrode is described, which contains the room temperature ionic liquid tri(tert-butyl)(decyl)phosphonium tetrafluoroborate as a binder. The advantages of this electrode are a high conductivity, very wide electrochemical window (5.4 V from 2.7 V to −2.7 V, one of the widest ever reported for RTILs), stability in time, and reproducibility.
ISSN:1042-6507
1563-5325
DOI:10.1080/10426507.2016.1217215