Synthesis and Structure of an Iron-Bromoalumanyl Complex with a Tri-Coordinated Aluminum Center

An iron-bromoalumanyl complex with a tri-coordinated aluminum was synthesized. Its CO-stretching frequencies are shifted to lower-frequency region compared to those of the related boryl and gallyl complexes. Theoretical investigations suggested the importance of the Br–Al mesomeric effect on the sta...

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Bibliographic Details
Published in:Bulletin of the Chemical Society of Japan 2016-10, Vol.89 (10), p.1184-1186
Main Authors: Agou, Tomohiro, Yanagisawa, Tatsuya, Sasamori, Takahiro, Tokitoh, Norihiro
Format: Article
Language:English
Subjects:
Aluminum
Iron
Stretching
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Summary:An iron-bromoalumanyl complex with a tri-coordinated aluminum was synthesized. Its CO-stretching frequencies are shifted to lower-frequency region compared to those of the related boryl and gallyl complexes. Theoretical investigations suggested the importance of the Br–Al mesomeric effect on the stability of the alumanyl complex.
ISSN:0009-2673
1348-0634
DOI:10.1246/bcsj.20160151