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Coordination-driven Nanostructures with Polyaromatic Shells

In contrast to broad applications of small aromatic rings and π-conjugated wire-like units, the use of large polyaromatic rings in coordination nanostructures has been less developed to date. This review article describes the recent progress of coordination-driven cages and capsules with multiple po...

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Published in:Chemistry letters 2017-02, Vol.46 (2), p.163-171
Main Authors: Yoshizawa, Michito, Yamashina, Masahiro
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Language:English
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description In contrast to broad applications of small aromatic rings and π-conjugated wire-like units, the use of large polyaromatic rings in coordination nanostructures has been less developed to date. This review article describes the recent progress of coordination-driven cages and capsules with multiple polyaromatic panels, such as anthracene, pyrene, and perylene derivatives. In the well-defined cavities, intriguing chemical phenomena can be observed through enhanced interactions with the polyaromatic frameworks.
doi_str_mv 10.1246/cl.160852
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subjects Anthracene
Aromatic compounds
Cages
title Coordination-driven Nanostructures with Polyaromatic Shells
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