Thermodynamic Analysis of the Formation of C8 Isomers in the Alkylation of Isobutane by Olefins

The process and results of a thermodynamic analysis of C 8 isomer formation upon the alkylation of isobutene by olefins using thermobaric dependence and an information model are presented. The experimental data were used to determine the probability of reaction in the 1-3 MPa pressure range. No sign...

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Bibliographic Details
Published in:Chemistry and technology of fuels and oils 2017, Vol.52 (6), p.646-655
Main Authors: Khamzin, Yu. A., Shiriyazdanov, R. R., Trapeznikova, E. F., Davletshin, A. R., Makhmutova, O. N., Vil’danov, F. Sh, Imashev, U. B., Rakhimov, M. N., Telyashev, E. G.
Format: Article
Language:English
Subjects:
Alkenes
Alkylation
Chemistry
Chemistry and Materials Science
Geotechnical Engineering & Applied Earth Sciences
Industrial Chemistry/Chemical Engineering
Isomers
Mineral Resources
Pressure dependence
Thermodynamics
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Summary:The process and results of a thermodynamic analysis of C 8 isomer formation upon the alkylation of isobutene by olefins using thermobaric dependence and an information model are presented. The experimental data were used to determine the probability of reaction in the 1-3 MPa pressure range. No significant change in the Gibbs energy was found to occur at pressures above 1 MPa.
ISSN:0009-3092
1573-8310
DOI:10.1007/s10553-017-0756-z